The one thing that is hard on gears is shifting while pedaling hard. You want to let up just a little, the rear is not as bad as the front. The other thing you don't want to do is run the chain at to great of an angle. You can use any gear on the rear when using the center chain ring in the front. You want to use only 1-4 with the small chain ring and the top 3 gears with the largest. Another important thing is keeping the chain clean and lubricated. Don't lube a dirty chain.
http://bicycletutor.com/gear-shifting/
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